Half-sandwich ruthenium(II)-arene complexes: synthesis, spectroscopic studies, biological properties, and molecular modeling
نویسندگان
چکیده
منابع مشابه
Synthesis, biological and molecular modeling studies of macrocyclic complexes of trivalent metal ions
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متن کاملThe half-sandwich 18- and 16-electron arene ruthenium iminophosphonamide complexes.
Novel half-sandwich 18ē and 16ē arene ruthenium iminophosphonamide complexes [(η6-C6Me6)RuCl{(R'N)2PR2}] (3a-c) and [(η6-C6Me6)Ru{(R'N)2PR2}]+(X-) (4a-c) (a, R = Ph, R' = p-Tol; b, R = Et, R' = p-Tol; c, R = Ph, R' = Me. X = BF4, PF6 or BArF4) were synthesized. The elongated Ru-Cl bond in the 18ē complexes is shown to dissociate even in apolar solvents to form the corresponding 16ē cations, whi...
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ژورنال
عنوان ژورنال: Journal of Coordination Chemistry
سال: 2019
ISSN: 0095-8972,1029-0389
DOI: 10.1080/00958972.2018.1553298